Attività

As the industry leader in phosphine ligands and catalysts for homogeneous catalysis, Solvay offers a range of phosphorus compounds used in a breadth of applications and markets. Our scalable phosphorus chemistry meets the unique requirements of reactions that are crucial to several manufacturing processes across markets and applications, including petrochemicals, life sciences, flavors and fragrances, agrochemicals, fine chemicals, and plastics and other polymers. And do you what is Phosphine Ligands?

Phosphines are a three-valent phosphorus compound and act as a “soft” σ-donating ligand with an unshared electron pair. This gives solubilization and stabilization to organometallic complexes by forming complexes with various transition metal species including latter-period transition metals and others, and is also used for controlling the reactivity and selectivity of the transition metal promoted reactions.

Electron density and bulkiness of phosphine ligands are greatly related to the reactivity of their forming metal complexes. Generally, the phosphine ligands with high electron density increase the reactivity of oxidative addition from a metal center, and their bulkiness improves the reductive elimination. For example, trialkylphosphines especially tert-butyl or cyclohexyl group substituted phosphines show the highest electron density while the electron density of triarylphosphines and phosphite are sequentially decreasing. On the other hand, as an index of the bulkiness of phosphine ligands, that of monodentate phosphine ligands shows the cone angle (θ) while bidentate phosphine ligands show the bite angle (ω). As the angle of the phosphine ligands is wider, their steric effect is greater and they are regarded as more bulky phosphine ligands. A monodentate phosphine ligand of tri(o-tolyl)phosphine, and bidentate phosphine ligands of 1,1′-bis(diphenylphosphino)ferrocene and Xantphos are known as representative bulky phosphine ligands. There are many different kinds of Phosphine Ligands, such as Chiral Phosphine Ligands, Chelated Phosphine Ligands, Biaryl Phosphine Ligand, Trisubstituted Phosphine Ligands and Other Phosphine Ligands.
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